The Chemical History of a Candle by Michael Faraday (the red fox clan .txt) 📖

will rise a second time. [The stop-cocks were then opened.] Those gases [referring to the gases first collected in the jar, and which had just been ignited by the electric spark] have disappeared, as you see: their place is vacant, and fresh gas has gone in. Water has been formed from them; and if we repeat our operation [repeating the last experiment], I shall have another vacancy, as you will see by the water rising. I always have an empty vessel after the explosion, because the vapour or gas into which that water has been resolved by the battery explodes under the influence of the spark, and changes into water; and by-and-by you will see in this upper vessel some drops of water trickling down the sides and collecting at the bottom.

We are here dealing with water entirely, without reference to the atmosphere. The water of the candle had the atmosphere helping to produce it; but in this way it can be produced independently of the air. Water, therefore, ought to contain that other substance which the candle takes from the air, and which, combining with the hydrogen, produces water.

Just now you saw that one end of this battery took hold of the copper, extracting it from the vessel which contained the blue solution. It was effected by this wire; and surely we may say, if the battery has such power with a metallic solution which we made and unmade, may we not find that it is possible to split asunder the component parts of the water, and put them into this place and that place? Suppose I take the poles—the metallic ends of this battery—and see what will happen with the water in this apparatus (fig. 20), where we have separated the two ends far apart.

[Illustration: Fig. 20.]

I place one here (at A), and the other there (at B), and I have little shelves with holes which I can put upon each pole, and so arrange them that whatever escapes from the two ends of the battery will appear as separate gases; for you saw that the water did not become vaporous, but gaseous. The wires are now in perfect and proper connection with the vessel containing the water; and you see the bubbles rising: let us collect these bubbles and see what they are. Here is a glass cylinder (O); I fill it with water and put it over one end (A) of the pile; and I will take another (H) and put it over the other end (B) of the pile. And so now we have a double apparatus, with both places delivering gas. Both these jars will fill with gas. There they go, that to the right (H) filling very rapidly; the one to the left (O) filling not so rapidly; and though I have allowed some bubbles to escape, yet still the action is going on pretty regularly; and were it not that one is rather smaller than the other, you would see that I should have twice as much in this (H) as I have in that (O). Both these gases are colourless; they stand over the water without condensing; they are alike in all things—I mean in all apparent things; and we have here an opportunity of examining these bodies and ascertaining what they are. Their bulk is large, and we can easily apply experiments to them. I will take this jar (H) first, and will ask you to be prepared to recognise hydrogen.

Think of all its qualities—the light gas which stood well in inverted vessels, burning with a pale flame at the mouth of the jar—and see whether this gas does not satisfy all these conditions. If it be hydrogen, it will remain here while I hold this jar inverted. [A light was then applied, when the hydrogen burnt] What is there now in the other jar? You know that the two together made an explosive mixture. But what can this be which we find as the other constituent in water, and which must therefore be that substance which made the hydrogen burn? We know that the water we put into the vessel consisted of the two things together. We find one of these is hydrogen: what must that other be which was in the water before the experiment, and which we now have by itself? I am about to put this lighted splinter of wood into the gas. The gas itself will not burn, but it will make the splinter of wood burn. [The Lecturer ignited the end of the wood, and introduced it into the jar of gas.] See how it invigorates the combustion of the wood, and how it makes it burn far better than the air would make it burn; and now you see by itself that every other substance which is contained in the water, and which, when the water was formed by the burning of the candle, must have been taken from the atmosphere. What shall we call it, A, B, or C? Let us call it O—call it "Oxygen:" it is a very good distinct-sounding name. This, then, is the oxygen which was present in the water, forming so large a part of it.

We shall now begin to understand more clearly our experiments and researches; because, when we have examined these things once or twice, we shall soon see why a candle burns in the air. When we have in this way analysed the water—that is to say, separated, or electrolysed its parts out of it—we get two volumes of hydrogen, and one of the body that burns it. And these two are represented to us on the following diagram, with their weights also stated; and we shall find that the oxygen is a very heavy body by comparison with the hydrogen. It is the other element in water.

I had better, perhaps, tell you now how we get this oxygen abundantly, having shewn you how we can separate it from the water. Oxygen, as you will immediately imagine, exists in the atmosphere; for how should the candle burn to produce water without it?

_____________________ | | | | 1 | 8 | | | | | | Oxygen. | Oxygen, . . . . 88.9 | | | | |_________| Hydrogen, . . . 11.1 | Hydrogen. | ——- | | 9 Water,. . . . . 100.0 | | | | | | |___________|

Such a thing would be absolutely impossible, and chemically impossible, without oxygen.

[Illustration: Fig. 21.]

Can we get it from the air? Well, there are some very complicated and difficult processes by which we can get it from the air; but we have better processes. There is a substance called the black oxide of manganese: it is a very black-looking mineral, but very useful, and when made red-hot it gives out oxygen. Here is an iron bottle which has had some of this substance put into it, and there is a tube fixed to it, and a fire ready made, and Mr. Anderson will put that retort into the fire, for it is made of iron, and can stand the heat. Here is a salt called chlorate of potassa, which is now made in large quantities for bleaching, and chemical and medical uses, and for pyrotechnic and other purposes. I will take some and mix it with some of the oxide of manganese (oxide of copper, or oxide of iron would do as well); and if I put these together in a retort, far less than a red heat is sufficient to evolve this oxygen from the mixture. I am not preparing to make much, because we only want sufficient for our experiments; only, as you will see immediately, if I use too small a charge, the first portion of the gas will be mixed with the air already in the retort, and I should be obliged to sacrifice the first portion of the gas, because it would be so much diluted with air; the first portion must therefore be thrown away. You will find in this case, that a common spirit-lamp is quite sufficient for me to get the oxygen, and so we shall have two processes going on for its preparation. See how freely the gas is coming over from that small portion of the mixture. We will examine it, and see what are its properties. Now, in this way we are producing, as you will observe, a gas just like the one we had in the experiment with the battery, transparent, undissolved by water, and presenting the ordinary visible properties of the atmosphere. (As this first jar contains the air, together with the first portions of the oxygen set free during the preparation, we will carry it out of the way, and be prepared to make our experiments in a regular, dignified manner.) And, inasmuch as that power of making wood, wax, or other things burn, was so marked in the oxygen we obtained by means of the voltaic battery from water, we may expect to find the same property here. We will try it You see there is the combustion of a lighted taper in air, and here is its combustion in this gas [lowering the taper into the jar]. See how brightly and how beautifully it burns! You can also see more than this,—you will perceive it is a heavy gas, whilst the hydrogen would go up like a balloon, or even faster than a balloon, when not encumbered with the weight of the envelope.

[Illustration: Fig. 22.]

You may easily see that although we obtained from water twice as much in volume of the hydrogen as of oxygen, it does not follow that we have twice as much in weight—because one is heavy, and the other a very light gas. We have means of weighing gases or air; but without stopping to explain, that, let me just tell you what their respective weights are. The weight of a pint of hydrogen is three-quarters of a grain; the weight of the same quantity of oxygen is nearly twelve grains. This is a very great difference. The weight of a cubit foot of hydrogen is one-twelfth of an ounce; and the weight of a cubit foot of oxygen is one ounce and a third. And so on we might come to masses of matter which may be weighed in the balance, and which we can take account of as to hundredweights and as to tons, as you will see almost immediately.

Now, as regards this very property of oxygen supporting combustion, which we may compare to air, I will take a piece of candle to shew it you in a rough way, and the result will be rough. There is our candle burning in the air: how will it burn in oxygen? I have here a jar of this gas, and I am about to put it over the candle for you to compare the action of this gas with that of the air. Why, look at it: it looks something like the light you saw at the poles of the voltaic battery. Think how vigorous that action must be! And yet, during all that action, nothing more is produced than what is produced by the burning of the candle in air. We have the same production of water, and the same phenomena exactly, when we use this gas instead of air, as we have when the candle is burnt in air.

But now we have got a knowledge of this new substance, we can look at it a little more distinctly, in order to satisfy ourselves that we have got a good general understanding of this part of the product of a candle. It is wonderful how great the supporting powers