The Chemical History of a Candle by Michael Faraday (the red fox clan .txt) 📖

next experiment with regard to this gas. What is its nature? Here is one of the vessels full, and we will try it, as we have done so many other gases, by combustion. You see it is not combustible, nor does it support combustion. Neither, as we know, does it dissolve much in water, because we collect it over water very easily. Then, you know that it has an effect, and becomes white in contact with lime-water; and when it does become white in that way, it becomes one of the constituents to make carbonate of lime or limestone.

The next thing I must shew you is, that it really does dissolve a little in water, and therefore that it is unlike oxygen and hydrogen in that respect I have here an apparatus by which we can produce this solution. In the lower part of this apparatus is marble and acid, and in the upper part cold water. The valves are so arranged that the gas can get from one to the other. I will set it in action now, and you can see the gas bubbling up through the water, as it has been doing all night long, and by this time we shall find that we have this substance dissolved in the water. If I take a glass and draw off some of the water, I find that it tastes a little acid to the mouth: it is impregnated with carbonic acid; and if I now apply a little lime-water to it, that will give us a test of its presence. This water will make the lime-water turbid and white, which is proof of the presence of carbonic acid.

Then it is a very weighty gas—it is heavier than the atmosphere. I have put their respective weights at the lower part of this table, along with, for comparison, the weights of the other gases we have been examining:—

                       Pint. Cubic Foot.
Hydrogen, . . . . 3/4 grains. 1/12 ounce.
Oxygen, . . . . 11-9/10 " 1-1/2 "
Nitrogen, . . . . 10-1/10 " 1-1/4 "
Air,. . . . . . 10-7/16 " 1-3/8 "
Carbonic acid, . . 16-1/3 " 1-9/10 "

A pint of it weighs 16-1/3 grains, and a cubic foot weighs 1-9/10 ounce, almost two ounces. You can see by many experiments that this is a heavy gas. Suppose I take a glass containing nothing else but air, and from this vessel containing the carbonic acid I attempt to pour a little of this gas into that glass; I wonder whether any has gone in or not. I cannot tell by the appearance, but I can in this way [introducing the taper]. Yes, there it is, you see; and if I were to examine it by lime-water, I should find it by that test also. I will take this little bucket, and put it down into the well of carbonic acid—indeed, we too often have real wells of carbonic acid—and now, if there is any carbonic acid, I must have got to it by this time, and it will be in this bucket, which we will examine with a taper. There it is, you see; it is full of carbonic acid.

[Illustration: Fig. 30.]

There is another experiment by which I will shew you its weight. I have here a jar suspended at one end of a balance—it is now equipoised; but when I pour this carbonic acid into the jar on the one side which now contains air, you will see it sink down at once, because of the carbonic acid that I pour into it. And now, if I examine this jar with the lighted taper, I shall find that the carbonic acid has fallen into it, and it no longer has any power of supporting the combustion. If I blow a soap-bubble, which of course will be filled with air, and let it fall into this jar of carbonic acid, it will float.

[Illustration: Fig. 31.]

But I shall first of all take one of these little balloons filled with air. I am not quite sure where the carbonic acid is; we will just try the depth, and see whereabouts is its level. There, you see, we have this bladder floating on the carbonic acid; and if I evolve some more of the carbonic acid, the bladder will be lifted up higher. There it goes—the jar is nearly full; and now I will see whether I can blow a soap-bubble on that, and float it in the same way. [The Lecturer here blew a soap-bubble, and allowed it to fall into the jar of carbonic acid, when it floated in it midway.] It is floating, as the balloon floated, by virtue of the greater weight of the carbonic acid than of the air. And now, having so far given you the history of the carbonic acid—as to its sources in the candle, as to its physical properties and weight—when we next meet I shall shew you of what it is composed, and where it gets its elements from.

LECTURE VI. CARBON OR CHARCOAL—COAL GAS—RESPIRATION AND ITS ANALOGY TO THE BURNING OF A CANDLE—CONCLUSION.

A lady, who honours me by her presence at these Lectures, has conferred a still further obligation by sending me these two candles, which are from Japan, and, I presume, are made of that substance to which I referred in a former lecture. You see that they are even far more highly ornamented than the French candles; and, I suppose, are candles of luxury, judging from their appearance. They have a remarkable peculiarity about them—namely, a hollow wick,—that beautiful peculiarity which Argand introduced into the lamp, and made so valuable. To those who receive such presents from the East, I may just say that this and such like materials gradually undergo a change which gives them on the surface a dull and dead appearance; but they may easily be restored to their original beauty, if the surface be rubbed with a clean cloth or silk handkerchief, so as to polish the little rugosity or roughness: this will restore the beauty of the colours. I have so rubbed one of these candles, and you see the difference between it and the other which has not been polished, but which may be restored by the same process. Observe, also, that these moulded candles from Japan are made more conical than the moulded candles in this part of the world.

I told you, when we last met, a good deal about carbonic acid. We found, by the lime-water test, that when the vapour from the top of the candle or lamp was received into bottles, and tested by this solution of lime-water (the composition of which I explained to you, and which you can make for yourselves), we had that white opacity which was in fact calcareous matter, like shells and corals, and many of the rocks and minerals in the earth. But I have not yet told you fully and clearly the chemical history of this substance—carbonic acid—as we have it from the candle, and I must now resume that subject. We have seen the products, and the nature of them, as they issue from the candle. We have traced the water to its elements, and now we have to see where are the elements of the carbonic acid supplied by the candle. A few experiments will shew this. You remember that when a candle burns badly, it produces smoke; but if it is burning well, there is no smoke. And you know that the brightness of the candle is due to this smoke, which becomes ignited. Here is an experiment to prove this: so long as the smoke remains in the flame of the candle and becomes ignited, it gives a beautiful light, and never appears to us in the form of black particles. I will light some fuel, which is extravagant in its burning. This will serve our purpose—a little turpentine on a sponge. You see the smoke rising from it, and floating into the air in large quantities; and, remember now, the carbonic acid that we have from the candle is from such smoke as that. To make that evident to you, I will introduce this turpentine burning on the sponge into a flask where I have plenty of oxygen, the rich part of the atmosphere, and you now see that the smoke is all consumed. This is the first part of our experiment; and now, what follows? The carbon which you saw flying off from the turpentine flame in the air is now entirely burned in this oxygen, and we shall find that it will, by this rough and temporary experiment, give us exactly the same conclusion and result as we had from the combustion of the candle. The reason why I make the experiment in this manner is solely that I may cause the steps of our demonstration to be so simple that you can never for a moment lose the train of reasoning, if you only pay attention. All the carbon which is burned in oxygen, or air, comes out as carbonic acid, whilst those particles which are not so burned shew you the second substance in the carbonic acid—namely, the carbon—that body which made the flame so bright whilst there was plenty of air, but which was thrown off in excess when there was not oxygen enough to burn it.

I have also to shew you a little more distinctly the history of carbon and oxygen, in their union to make carbonic acid. You are now better able to understand this than before, and I have prepared three or four experiments by way of illustration. This jar is filled with oxygen, and here is some carbon which has been placed in a crucible, for the purpose of being made red-hot. I keep my jar dry, and venture to give you a result imperfect in some degree, in order that I may make the experiment brighter. I am about to put the oxygen and the carbon together. That this is carbon (common charcoal pulverised), you will see by the way in which it burns in the air [letting some of the red-hot charcoal fall out of the crucible]. I am now about to burn it in oxygen gas, and look at the difference. It may appear to you at a distance as if it were burning with a flame; but it is not so. Every little piece of charcoal is burning as a spark, and whilst it so burns it is producing carbonic acid. I specially want these two or three experiments to point out what I shall dwell upon more distinctly by-and-by—that carbon burns in this way, and not as a flame.

Instead of taking many particles of carbon to burn, I will take a rather large piece, which will enable you to see the form and size; and to trace the effects very decidedly. Here is the jar of oxygen, and here is the piece of charcoal, to which I have fastened a little piece of wood, which I can set fire to, and so commence the combustion, which I could not conveniently do without. You now see the charcoal burning, but not as a flame (or if there be a flame, it is the smallest possible one, which I know the cause of—namely, the formation of a little carbonic oxide close upon the surface of the carbon). It goes on burning, you see, slowly producing carbonic acid by the union of this carbon or charcoal (they are equivalent terms) with the oxygen. I have here another piece of charcoal, a piece of bark, which has the quality of being blown to pieces—exploding as it burns. By the effect of the heat, we shall reduce the lump of carbon into particles that will fly off; still every particle, equally with the whole mass, burns in this peculiar way: it burns as a coal, and not like a flame. You observe a multitude of little combustions going on, but no flame. I do not know a finer experiment than this, to shew that carbon burns with a spark.

Here, then, is carbonic acid formed from its elements. It is produced at once; and if we examined it by lime-water, you will see that we have the same substance which I have previously described to you. By putting together 6 parts of carbon by weight (whether it comes from the flame of a candle or from powdered charcoal) and 16